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Engineering, Energy, Transport AIC

space SCIENTIFIC JOURNALS OF VINNITSA NATIONAL AGRARIAN UNIVERSITY

Issue №: 1 (128)

Published: 2025.03.31
DOI: 10.37128/2520-6168-2025-1


Description:
The journal solves the problems of creation and improvement of machinery and technologies for agriculture: 131 - Applied Mechanics, 132 - Materials Science, 133 - Industrial Engineering, 141 - Power Engineering, Electrical Engineering and Electromechanics, 208 - Agricultural Engineering.

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OPTIMIZATION OF COMPACT TiO₂ PHOTOCATALYSTS FOR WATER PURIFICATION IN AGRICULTURAL OPERATIONS

DOI: 10.37128/2520-6168-2025-1-11
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Serhii BURLAKA – Doctor of Philosophy in Industrial Mechanical Engineering, Associate Professor of the Department of Engineering Mechanics and Technological Processes in the Agricultural and Industrial Complex of Vinnytsia National Agrarian University (3 Sonyachna St., Vinnytsia, Ukraine, 21008, e-mail: ipserhiy @ gmail . com , https://orcid.org/0000-0002-4079-4867)

Dmytro DATSIUK – Doctor of Philosophy in Industrial Engineering, Senior Lecturer at the Department of Engineering Mechanics and Technological Processes in the Agro-Industrial Complex of Vinnytsia National Agrarian University (St. Soniachna, 3, Vinnytsia, Ukraine, 21008, e-mail: datsiuk.vnay@gmail.com, https://orcid.org/0000-0002-4614-2245 ).

Volodymyr PANASENKO – Candidate of Technical Sciences, Senior Lecturer of the Department of Engineering Mechanics and Technological Processes in the Agro-Industrial Complex at Vinnytsia National Agrarian University (Soniachna St., 3, Vinnytsia, Ukraine, 21008, e-mail: panasenkovv@gmail.com, https://orcid.org/0009-0002-3928-9473).

Annotation

Article dedicated development and optimization compact photocatalytic modules on basis titanium (IV) oxide (TiO₂) for cleaning water that used in agrotechnical operations , in particular for hydration seed under time sowing cereals cultures in seeders . The work solves the problem of providing clean water in field conditions, where traditional treatment methods are cumbersome or economically unprofitable. A complex mathematical model is proposed that describes the nonlinear kinetics of photocatalytic decomposition of organic pollutants, taking into account the intensity of ultraviolet light (5–20 mW/cm²), the size of TiO₂ particles (10–50 nm), the concentration of the catalyst (0.5–2.0 g/l) and the temperature (20–40 °C). The model is based on the Langmuir-Hinshelwood equation, supplemented by dependencies on the catalyst surface and activation energy, and is solved numerically by the Runge-Kutta method. Experiments were carried out using TiO₂ nanoparticles (anatase) and a model pollutant (methylene blue, 10 mg/l) in a laboratory module that simulates the operation of seeders. The results confirm the high accuracy of the model: the optimal parameters (I = 15 mW/cm², d = 25 nm, [TiO₂] = 1.0 g/l, T = 30 °C) provide a cleaning efficiency of 38% in 15 minutes, reducing the concentration of contaminants to 6.2 mg/l, which is sufficient for agrotechnical needs. The data are presented in tables and graphs that illustrate the influence of key variables. The optimized system is suitable for integration into seed drills such as Horsch Pronto or John Deere 1890, increasing seed germination in arid regions. The work outlines the prospects for using solar energy and modified TiO₂ to further improve the technology, contributing to sustainable agriculture.

Keywords: photocatalysis, TiO₂ (titanium(IV) oxide), water purification, agrotechnical operations, grain planters, mathematical modeling, nonlinear kinetics, ultraviolet light.

List of references

1.    Evans, A.E., Mateo-Sagasta, J. Qadir, M. Boelee, E. Ippolito, A. (2019). Agricultural Water Pollution: Key Knowledge Gaps and Research Needs. Curr. Opin. Environ. Sustain, 36, 20–27. [in English].
2.    Loeb, SK., Alvarez, PJJ, Brame, JA., Cates, EL., Choi, W., Crittenden, J., Dionysiou, DD, Li, Q., Li-Puma, G., Quan, X., (2019).The Technology Horizon for Photocatalytic Water Treatment: Sunrise or Sunset? Environ. Sci. Technol, 53, 2937–2947. [in English].
3.    Krysa, J., Waldner, G., Měšt'ánková, H., Jirkovský, J., Grabner, G. (2006). Photocatalytic Degradation of Model Organic Pollutants on an Immobilized Particulate TiO2 Layer. Roles of Adsorption Processes and Mechanistic Complexity. Appl. Catal. B Environ, 64, 290–301. [in English].
4.    Shen, Y., Li, F., Li, S., Liu, D., Fan, L., Zhang, Y. (2012). Electrochemically Enhanced Photocatalytic Degradation of Organic Pollutants on β-PbO2-TNT/Ti/TNT Bifunctional Electrode. Int. J. Electrochem, 7, 8702–8712. [in English].
5.    Bielan, Z., Sulowska, A., Dudziak, S., Siuzdak, K., Ryl, J., Zielińska-Jurek, A. (2020). Defective TiO2 Core-Shell Magnetic Photocatalyst Modified with Plasmonic Nanoparticles for Visible Light-Induced Photocatalytic Activity. Catalysts, 10, 672. [in English].
6.    Claes, T., Fransen, S., Degrève, J., van Gerven, T., Enis Leblebici, M. (2020). Kinetic Optimization of Multilayered Photocatalytic Reactors. Chem. Eng. J., 421, 127794. [in English].
7.    Enesca, A. (2021). The Influence of Photocatalytic Reactors Design and Operating Parameters on the Wastewater Organic Pollutants Removal–A Mini-review. Catalysts, 11, 556. [in English].
8.    Yaropud, V., Honcharuk, I., Datsiuk, D., Aliyev E. (2020). The model for random packaging of small-seeded crops' seeds in the reservoir of selection seeders sowing unit. Agraarteadus, 33 (1), 199–208. https://dx.doi.org/10.15159/jas.22.08. [in English].
9.    Souza, RP., Freitas, TKFS., Domingues, FS., Pezoti, O., Ambrosio, E., Ferrari-Lima, AM., Garcia, JC. (2016). Photocatalytic Activity of TiO2, ZnO and Nb2O5 Applied to Degradation of Textile Wastewater. J. Photochem. Photobiol. A Chem, 329, 9–17. [in English].
10.    Burlaka, S.A., Galushchak, O.O., Borysyuk, D.V., Baranov, V.A. (2024). Study of the trajectory of fuel particles in a mixer. Engineering, Energy, Transport AIC, 1(124), 89–94. DOI: 10.37128/2520-6168-2024-1-10. [in English].
11.    Yaropud, V.M., Datsyuk, D.A., Teslyuk, G.V. (2023). Using the discrete element method in modeling the movement and placement of seeds of small-seeded crops. Vibrations in Engineering and Technologies, 1(108), 73–82. DOI: 10.37128/2306-8744-2023-1-8. [in English].
12.    Yaropud, V., Aliyev, E., Datsyuk, D. (2021). Methods of numerical modeling of sowing apparatus of selection seeder of small-seed crops. Machinery and Energetics, 12(3), 121–127. [in English].
13.    Rutkevych, V., Kupchuk, I., Yaropud, V., Hraniak, V., Burlaka, S. (2022). Numerical simulation of the liquid distribution problem by an adaptive flow distributor. Przeglad Elektrotechniczny, 98(2), 64–69. [in English].
14.    Burlaka, S., Boretska, T., Syvak, V. (2024). The use of ionization in technological processes. Bulletin of the Khmelnytsky National University. Series: Technical Sciences, 5(341), 221–226. [in English].

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About journal

Topics of the journal:

131 - Applied Mechanics

132 - Materials Science

133 - Industry engineering

141 - Power engineering, electrical engineering and electromechanics

208 - Agricultural engineering

The magazine "Engineering, Energy, Transport AIC" is included in the list of scientific professional editions of Ukraine on technical sciences

(Category "Б", Order of the Ministry of Education and Science of Ukraine dated 02.07.2020 №886)

Old version of site: http://tetapk.vsau.edu.ua, http://techjournal.vsau.org

According to the decision of National Council of Television and Radio Broadcasting of Ukraine from 25.04.2024 No. 1337 the scientific journal «Engineering, Energy, Transport AIC» has the ID of the Media R30-05173.

The journal "Engineering, Energy, Transport AIC" is indexed according to the following databases and catalogs:

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Key information:
ISSN (print): 2520-6168
DOI: 10.37128/2520-6168

Certificate of state registration of mass media: No. 21906-11806 P dated 03/12/2016.

Founder of the journal: Vinnytsia National Agrarian University

Editor-in-chief: Olexii TOKARCHUK - Candidate of Technical Sciences, Associate Professor, VNAU (Vinnytsia)

Deputy Editor-in-Chief: Vitalii YAROPUD - Candidate of Technical Sciences, Associate Professor, VNAU (Vinnytsia)

Executive Secretary: Yuriy POLIEVODA - Candidate of Technical Sciences, Associate Professor, VNAU (Vinnytsia)

Members of the Editorial Board:

Oleg TSURKAN – Doctor of Technical Sciences, Full Professor, Vinnytsia National Agrarian University (Ukraine)

Volodymyr BULGAKOV – Doctor of Technical Sciences, Full Professor, Acad. NAAS, National University of Life and Environmental Sciences of Ukraine (Ukraine)

Rostislav ISKOVICH-LOTOTSKY  – Doctor of Technical Sciences, Full Professor, Vinnytsia National Technical University (Ukraine)

Yuliia SALENKO – Doctor of Technical Sciences, Full Professor, Kremenchuk Mykhailo Ostrohradskyi National University (Ukraine)

Igor KUPCHUK – Candidate of Technical Sciences, Associate Professor, Vinnytsia National Agrarian University (Ukraine)    

Serhii SHARHORODSKYI – Candidate of Technical Sciences, Associate Professor, Vinnytsia National Agrarian University (Ukraine)

Valerii HRANIAK – Candidate of Technical Sciences, Associate Professor, Vinnytsia National Agrarian University (Ukraine)

Anatoly SPIRIN – Candidate of Technical Sciences, Associate Professor, Vinnytsia National Agrarian University (Ukraine)

Olena SOLONA  – Candidate of Technical Sciences, Associate Professor, Vinnytsia National Agrarian University (Ukraine)

Igor TVERDOKHLIB – Candidate of Technical Sciences, Associate Professor, Vinnytsia National Agrarian University (Ukraine)

Yaroslav IVANCHUK – Doctor of Technical Sciences, Full Professor, Vinnytsia National Technical University (Ukraine)

Foreign members of the editorial board

Jordan Todorov MAXIMOV – Doctor of Technical Sciences, Full Professor, Technical University of Gabrovo (Bulgaria)   

Audrius ŽUNDA – Ph.D., Associate Professor, Vytautas Magnus University (Kaunas, Lithuania)

 

Type of publication: journal

Kind of publication: scientific

Publication status: domestic

Year of foundation: 1997

Periodicity: 4 times per year

Volume: 18-20 conv. print. sheet (А4)

ISSN: 2520-6168 (print version), (online version)

Language of publication: (mixed languages) Ukrainian, English

The sphere of distribution and category of readers: national, foreign, faculty, scientists, entrepreneurs.

The periodical edition is included to the List of scientific professional publications of Ukraine on technical sciences, approved by order of the Ministry of Education and Science of Ukraine in 05.16.2016, No. 515.

The journal "Engineering, Energy, Transport AIC" is included in the "Catalog of Ukrainian Publications".

Subscription to the journal can be issued in each post office. The subscription index is 99720.

History of journal:

It was founded in 1997 under the title "Bulletin of the Vinnitsa State Agricultural Institute." According to the Decree of the Presidium of the Higher Attestation Commission of Ukraine of September 11, 1997, this publication received the status of a professional in which it is allowed to publish the main results of dissertation researches.

In 2001-2014 the journal published under the title “Collection of scientific works of Vinnytsia National Agrarian University. Series: Technical Sciences "(Certificate of State Registration of Mass Media KV No. 16644-5116 PR of 04/30/2010).

Since 2015 journal has title "Engineering, Energy, Transport AIC" (Certificate of State Registration of Mass Media No. 21906-11806 P dated 03/12/2016).