
Issue №: 1 (128)
The journal solves the problems of creation and improvement of machinery and technologies for agriculture: 131 - Applied Mechanics, 132 - Materials Science, 133 - Industrial Engineering, 141 - Power Engineering, Electrical Engineering and Electromechanics, 208 - Agricultural Engineering.
PROSPECTS AND PROBLEMS OF BIODIESEL FUEL PRODUCTION
Vadym RYABOSHAPKA – Candidate of Technical Sciences, Senior Lecturer of the Department of Agricultural Engineering and Technical service of Faculty of Engineering and Technology, Vinnytsia National Agrarian University (3, Soniachna St., Vinnytsia, 21008, Ukraine, email: vadym@vsau.vin.ua, https://orcid.org/0000-0003-1812-1030).
Vadym IVATSKO – Recipient of the Third Educational and Scientific Level of the Department of Agricultural Engineering and Technical Service of Faculty of Engineering and Technology Vinnytsia National Agrarian University (3, Soniachna St., Vinnytsia, 21008, Ukraine, email: ivatsko95@gmail.com, https://orcid.org/0009-0001-4793-9379).
The article examines the physicochemical properties of fuels for internal combustion engines, focusing on key aspects such as elemental composition, heat of combustion, density, viscosity, etc. The prerequisites and stages of developing alternative fuels, particularly for compression ignition engines, are analyzed, with biodiesel fuel taking a prominent place. Chemically, biodiesel consists of methyl esters of fatty acids (lipids) and, due to its physicochemical properties, closely resembles conventional diesel fuel, allowing for mixing in various proportions. The paper discusses the most well-known biodiesel production methods, including transesterification (conventional, supercritical, enzymatic), pyrolysis, and hydrogenation (second-generation biodiesel), providing an overview of the mechanisms involved. The classical transesterification process is identified as the most promising for Ukraine. The study outlines the methods of classical transesterification and presents a schematic of the process. The article also describes the nomenclature of equipment for biodiesel production. It provides technical characteristics of some devices, including the BDD-200 biodiesel production line used in the alternative energy laboratory of Vinnytsia National Agrarian University. Scientific research on biodiesel production in Ukraine and key authors in this field are reviewed. Special attention is given to raw material resources for biodiesel fuel production. The study elaborates on classical transesterification technologies, including intermolecular and intramolecular transesterification, and alcoholysis, presenting fundamental chemical reactions involving methanol or ethanol. The advantages and disadvantages of various catalysts, such as potassium hydroxide and sodium hydroxide, are also discussed. This scientific paper presents the results of the initiative research project 0122U002187.
1. Okocha, A.I., Antypenko, A.M. (1996). Fuel, lubricants and other operational materials. Kyiv: Harvest [in Ukrainian].
2. Anisimov, V.F., Hunko, I.V., & Ryaboshapka, V.B. (2022). Development of a method for determining the fatty acid composition and lower calorific value of biodiesel fuel. Engineering, Energy, Transport AIC, 4 (119), 5–15. DOI: 10.37128/2520-6168-2022-4-1. [in Ukrainian].
3. Yakovleva, A.V., Boichenko, S.V., Hudz, A.V., & Zubenko, S.O. (2020). Physicochemical properties of biodiesel fuels based on ethyl esters of mustard oil. Kataliz ta naftokhimiia, 29, 24–31. doi.org/10.15407/kataliz2020.29.027. [in Ukrainian].
4. Zavody ta ustanovky z vyrobnytstva dyzelnoho biopalyva abo biodyzelia. Naukovo-vyrobnycha kompaniia Tovarystvo z obmezhenoiu vidpovidalnistiu Eleron : veb-sait. URL: http://www.biodiesel.co.ua/ (data zvernennia: 07.12.2024). [in Ukrainian].
5. Obladnannia ta osnovni vuzly zavodu z vyrobnytstva dyzelnoho biopalyva abo biodyzelia. Naukovo-vyrobnycha kompaniia Tovarystvo z obmezhenoiu vidpovidalnistiu Eleron : veb-sait. URL: http://www.biodiesel.co.ua/oborudovanie.htm (data zvernennia: 07.12.2024). [in Ukrainian].
6. Semenov, V. (2007). Biodiesel can be used in diesel engines. Kharchova i pererobna promyslovist, 4, 4–5. [in Ukrainian].
7. Semenov, V.H., Marchenko, A.P., Semenova, D.U., & Linkov, O.Yu. (2000). Research into the physicochemical properties of alternative biofuels based on rapeseed oil. Mashynobuduvannia: Visnyk Kharkivskoho derzhavnoho politekhnichnoho universytetu. Zbirnyk nauk. Prats, 101., 159–163.
8. Hrabar, I. H., Kolodnytska, R. V., & Semenov, V. H. (2011). Oils based on oils for diesel engines. Zhytomyr: ZhDTU. [in Ukrainian].
9. Lebedyev, A.T., & Shulyak M.L. (2011). The influence of coking of nozzle holes of engine injectors when operating on alternative fuels on the traction and energy performance of MTA. Mekhanika ta mashynobuduvannya, Х., 128–136. [in Ukrainian].
10. Shuliak, M.L. (2012). Increasing the efficiency of machine and tractor units using biodiesel fuels. Dissertation of the candidate of technical sciences Kharkiv: Petro Vasylenko KhNTUSG. [in Ukrainian].
11. Nadykto, V.T., Didur, V.A., & Fedorenko V.V. (2008). The impact of biodiesel on MTA performance. Naukovo-tekhnichnyi zhurnal ”Tekhnika APK”, 01 (January), 27–29. [in Ukrainian].
12. Nadykto, V.T., & Shabala, M.O. Technology and efficiency of growing oil crops for biodiesel production. Pratsi Tavriiskoho derzhavnoho ahrotekhnolohichnoho universytetu, 8(6), 25–28. [in Ukrainian].
13. Blium, Ya.B., Heletukha, H.H., Hryhoriuk, I.P., Dmytruk, K.V., Dubrovin, V.O., Yemets, A.I., & Zabarnyi, H.M., et al. (2010). Biological resources and biofuel production technologies. К: «Ahrar Media Hrup» [in Ukrainian].
14. Melnychuk, M.D., Dubrovin, V.O., Myronenko, V.H., Polishchuk, V.M., Kravchuk, V.I., Hrynko, P.V., & Burylko, A.V. (2011). Integrated energy-saving systems for the production and use of solid and liquid biofuels in the agro-industrial complex. Recommendations for agro-industrial enterprises of Ukraine. К: «Ahrar Media Hrup». [in Ukrainian].
15. Holub, H.A., Pavlenko, M.Yu., & Chuba, V.V. (2017). Production and use of diesel biofuels. Mechanical and technological bases. H.A. Holub (Ed.). Kyiv: NULESU of Ukraine. [in Ukrainian].
16. Chaikivskyi, T.V., Nikitishyn, Ye. Yu., Ivasiv, V. V., & Sarabun O. Ya. (2009). Obtaining biofuels from sunflower oil and ethyl alcohol. Scientific bulletin of UNFU, 19(2), 114–117. [in Ukrainian].
17. Topilin, H. Ye., Ked, Y.A. (2008). Two-stage purification of vegetable oil. Agrarian Bulletin of the Black Sea Littoral, 45, 170–174. [in Ukrainian].
18. Topilin, H.Ye., Umynskyi, S.M. (2008). Utility model patent UA32176 C11B3/00. Plant for microfiltration of vegetable oils. Claimed 10.12.2007. Publ. 12.05.2008. Bull. № 9. [in Ukrainian].
19. Hrabar, I.H., Arystarkhova, E.O., Kolodnytska R.V. (2002). Using rapeseed oil as automotive fuel (problems and prospects). Visnyk ZhITI, 2, 3–7. [in Ukrainian].
20. Hrabar, I.H., Ilchenko, A.V., Kolodnytska, R.V. (2004). Change in consumption of motor fuels with rapeseed oil additives. Visn. ZhDTU, 2(29), 19–24 [in Ukrainian].
21. Poliakov, A.P., Halushchak, D.O., Halushchak, O.O., & Vdovychenko O.V. (2017). Investigation of the impact of a car load on fuel consumption when using the engine power system with a change in the composition of a mixture of diesel and biodiesel fuels. Visnyk mashynobuduvannia ta transportu, 1, 84– 89 [in Ukrainian].
22. Poliakov, A.P., Halushchak, D.O., & Vdovychenko O.V. (2015). Justification of the selection of criteria for assessing the efficiency of converting a car engine to operate on a mixture of diesel and biodiesel fuels with a change in its composition. Engineering, Energy, Transport AIC, 15 (2), 124–127. [in Ukrainian].
23. Poliakov, A.P., & Halushchak, D.O. (2014). Study of the impact of converting a car's engine to run on biodiesel fuel on its performance. Naukovi notatky, 46, 431–438 [in Ukrainian].
24. Hryhorii KALETNIK, holova Komitetu Verkhovnoi Rady Ukrainy z pytan ahrarnoi polityky ta zemelnykh vidnosyn. Vyrobnytstvo ta spozhyvannia biopalyv – perspektyva enerhetychnoi bezpeky Ukrainy. Holos Ukrainy. URL: http://www.golos.com.ua/article/99615/ (data zvernennia: 07.12.2024) [in Ukrainian].
25. Kaletnik, H., Mazur, V., Gunko, I., Ryaboshapka, V., Bulgakov, V., Raide, V., Ilves, R., Olt, J. (2020). Study on performance of compression engine operated by biodiesel fuel. Agronomy Research, 18(S1), 862–887 [in English].
26. Kaletnik, H., Pilvere, I., Nikolaenko, S., Bulgakov, V. (2017). Investigation of Biofuel Production Possibilities For Stabilisation of Agro-Industrial Complex of Ukraine. 16th International Scientific Conference: Engineering for Rural Development, 1250–1256. [in English].
27. Kaletnik, G. (2008). Legal support perfection in biofuel market functioning in Ukraine. Actual Problems of Economics, 12, 48–52. [in English].
28. Ryaboshapka, V.B. (2023). Current status and prospects of scientific research on the transition of diesel engines to biodiesel fuel. Engineering, Energy, Transport AIC, 4 (123), 97–105 [in Ukrainian].
29. Dolinskyi, A.A., Hrabov, L.M., Mershchii, V.I., & Shmatok, O.I. (2008). Production of energy sources from renewable plant raw materials. Enerhetyka ta elektryfikatsiia. Naukovyi zhurnal, 9, 44–50 [in Ukrainian].
About journal
131 - Applied Mechanics
132 - Materials Science
133 - Industry engineering
141 - Power engineering, electrical engineering and electromechanics
208 - Agricultural engineering
The magazine "Engineering, Energy, Transport AIC" is included in the list of scientific professional editions of Ukraine on technical sciences
(Category "Б", Order of the Ministry of Education and Science of Ukraine dated 02.07.2020 №886)
Old version of site: http://tetapk.vsau.edu.ua, http://techjournal.vsau.org
According to the decision of National Council of Television and Radio Broadcasting of Ukraine from 25.04.2024 No. 1337 the scientific journal «Engineering, Energy, Transport AIC» has the ID of the Media R30-05173.
The journal "Engineering, Energy, Transport AIC" is indexed according to the following databases and catalogs:
Certificate of state registration of mass media: No. 21906-11806 P dated 03/12/2016.
Founder of the journal: Vinnytsia National Agrarian University
Editor-in-chief: Olexii TOKARCHUK - Candidate of Technical Sciences, Associate Professor, VNAU (Vinnytsia)
Deputy Editor-in-Chief: Vitalii YAROPUD - Candidate of Technical Sciences, Associate Professor, VNAU (Vinnytsia)
Executive Secretary: Yuriy POLIEVODA - Candidate of Technical Sciences, Associate Professor, VNAU (Vinnytsia)
Members of the Editorial Board:
Oleg TSURKAN – Doctor of Technical Sciences, Full Professor, Vinnytsia National Agrarian University (Ukraine)
Volodymyr BULGAKOV – Doctor of Technical Sciences, Full Professor, Acad. NAAS, National University of Life and Environmental Sciences of Ukraine (Ukraine)
Rostislav ISKOVICH-LOTOTSKY – Doctor of Technical Sciences, Full Professor, Vinnytsia National Technical University (Ukraine)
Yuliia SALENKO – Doctor of Technical Sciences, Full Professor, Kremenchuk Mykhailo Ostrohradskyi National University (Ukraine)
Igor KUPCHUK – Candidate of Technical Sciences, Associate Professor, Vinnytsia National Agrarian University (Ukraine)
Serhii SHARHORODSKYI – Candidate of Technical Sciences, Associate Professor, Vinnytsia National Agrarian University (Ukraine)
Valerii HRANIAK – Candidate of Technical Sciences, Associate Professor, Vinnytsia National Agrarian University (Ukraine)
Anatoly SPIRIN – Candidate of Technical Sciences, Associate Professor, Vinnytsia National Agrarian University (Ukraine)
Olena SOLONA – Candidate of Technical Sciences, Associate Professor, Vinnytsia National Agrarian University (Ukraine)
Igor TVERDOKHLIB – Candidate of Technical Sciences, Associate Professor, Vinnytsia National Agrarian University (Ukraine)
Yaroslav IVANCHUK – Doctor of Technical Sciences, Full Professor, Vinnytsia National Technical University (Ukraine)
Foreign members of the editorial board
Jordan Todorov MAXIMOV – Doctor of Technical Sciences, Full Professor, Technical University of Gabrovo (Bulgaria)
Audrius ŽUNDA – Ph.D., Associate Professor, Vytautas Magnus University (Kaunas, Lithuania)
Type of publication: journal
Kind of publication: scientific
Publication status: domestic
Year of foundation: 1997
Periodicity: 4 times per year
Volume: 18-20 conv. print. sheet (А4)
ISSN: 2520-6168 (print version), (online version)
Language of publication: (mixed languages) Ukrainian, English
The sphere of distribution and category of readers: national, foreign, faculty, scientists, entrepreneurs.
The periodical edition is included to the List of scientific professional publications of Ukraine on technical sciences, approved by order of the Ministry of Education and Science of Ukraine in 05.16.2016, No. 515.
The journal "Engineering, Energy, Transport AIC" is included in the "Catalog of Ukrainian Publications".
Subscription to the journal can be issued in each post office. The subscription index is 99720.
It was founded in 1997 under the title "Bulletin of the Vinnitsa State Agricultural Institute." According to the Decree of the Presidium of the Higher Attestation Commission of Ukraine of September 11, 1997, this publication received the status of a professional in which it is allowed to publish the main results of dissertation researches.
In 2001-2014 the journal published under the title “Collection of scientific works of Vinnytsia National Agrarian University. Series: Technical Sciences "(Certificate of State Registration of Mass Media KV No. 16644-5116 PR of 04/30/2010).
Since 2015 journal has title "Engineering, Energy, Transport AIC" (Certificate of State Registration of Mass Media No. 21906-11806 P dated 03/12/2016).